Search for: All records

Abstract Radiocarbon (¹⁴C) measurements on dissolved inorganic carbon (DIC) are a powerful tool to trace water masses and carbon cycling in the ocean. Existing methodologies to determine the¹⁴C content of seawater DIC requires large volumes of sample (usually >100 mL) and specialized graphitization techniques to achieve the accuracy and precision needed for meaningful data interpretation. The advancement of the CO₂gas ionization accelerator mass spectrometry (AMS) technique today allows routine¹⁴C measurements on small samples (<100 µgC) and may thus permit reducing the sample volumes needed to determine¹⁴C content of seawater DIC to ∼2 mL. The proposed method utilizes the carbonate handling system (CHS), gas interface system (GIS) and MICADAS AMS, and provides good accuracy but reduced precision compared to established methods. Good accuracy is shown by comparing results for a marine in-house DIC standard and a DIC seawater profile from Antarctica between the proposed CHS-GIS-MICADAS approach and reference measurements conducted on the same material at established laboratories (ETH and NOSAMS). Further, two sedimentary porewater profiles from a fjord system in Svalbard are presented. Despite good agreement, the precision of the CHS-GIS-MICADAS approach is reduced, potentially limiting possible interpretations on seawater DIC. Nonetheless, the reduction of sample volumes proves particularly helpful to analyze porewater DIC from sediment cores, where sample material is notoriously limited, reduces the required amounts of toxic HgCl₂and simplifies expedition logistics. 

Abstract. We present a global atlas of downcore foraminiferal oxygen and carbon isotope ratios available at https://doi.org/10.1594/PANGAEA.936747(Mulitza et al., 2021a). The database contains 2106 published and previously unpublished stable isotope downcore records with 361 949 stable isotopevalues of various planktic and benthic species of Foraminifera from 1265 sediment cores. Age constraints are provided by 6153 uncalibratedradiocarbon ages from 598 (47 %) of the cores. Each stable isotope and radiocarbon series is provided in a separate netCDF file containingfundamental metadata as attributes. The data set can be managed and explored with the free software tool PaleoDataView. The atlas will provideimportant data for paleoceanographic analyses and compilations, site surveys, or for teaching marine stratigraphy. The database can be updated withnew records as they are generated, providing a live ongoing resource into the future. 

The atlas contains a collection of 2,106 published and previously unpublished downcore stable isotope records of various planktonic and benthic species of foraminifera from 1,265 globally distributed sediment cores. Uncalibrated radiocarbon dates are provided for 598 cores in the collection. Each stable isotope and radiocarbon series is stored in a separate netCDF file containing fundamental meta data as attributes. The data set can be further explored and analyzed with the free software tool PaleoDataView (Langner, M. and Mulitza, S.: Clim. Past, 15, 2067–2072, https://doi.org/10.5194/cp-15-2067-2019). WA_Foraminiferal_Isotopes_2022.zip contains 2006 stable isotope records (in netCDF format) and 598 radiocarbon records (in netCDF format). The folder structure in the file should be preserved and is required to use the collection with the software PaleoDataView.